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MCS
TECHNOLOGY
SYSTEM COMPONENTS
The
MCS is comprised of a heater base assembly with treatment
trays, a vacuum blower system and
an air emission control system.
HEAT
SOURCE
The MCS system uses infrared radiation to generate the thermal
energy necessary to desorb the target compounds. The energy
transfer efficiency of an infrared system exceeds that of
a "conventional" low temperature thermal desorption
system. In general, other systems use a direct or indirect
energy source to heat the air in the desorption chamber and
transfer the heat to the matrix using a countercurrent flow.
Heat transfer is mainly by convection. Air has relatively
low thermal conductivity and specific heat values, which tend
to result in lower energy transfer efficiency for the "conventional"
systems compared to the MCS.
Attached
to the underside of the steel base are 8 propane-fired infrared
heaters. When the trays are loaded into the steel base, the
heaters are approximately ten inches below the surface of
the matrix. The fuel source is typically high pressure liquid
(2-4 psi) propane or other suitable gas.
The
propane-fired heaters heat an array of metal tubes to a temperature
between 1,100° to 1,300° F. At this temperature, the
metal tubes emit electromagnetic energy in the infrared spectrum.
This generated infrared energy is directed upward to the bottom
of the matrix. Within 10 to 15 minutes, the surface of the
matrix (bottom 4 inches) is heated from 200° to 800°
F). System temperature, which plateaus until 95% or more of
the water is driven off, reaches 300° F within 70 minutes.
Ultimately, the matrix can be heated to temperatures as high
as 1,100° F. The degree of heating is primarily dependent
upon the moisture content and type of matrix (i.e. amount
of clay/silt/sand). Average energy generation of the MCS system
is between 1.7 to 2.0 million BTU/hr.
TREATMENT
TRAYS/CHAMBER
The matrix treatment trays are carbon steel containers that
measure 8' x 8' x 1.5'. The trays have a screened bottom which
supports the matrix and allows the air to flow through the
material. The tray has two forklift pockets in its base below
the screen and a dump gate at the opposite end. The base of
the chamber contains 8 four-inch steel heater tubes. The capacity
of each treatment tray is 2.5 cubic yards. Two trays are loaded
into one heater base and a gasketed steel manifold is mechanically
lowered to form a seal between the top manifold and the trays.
This forms the treatment chamber.
VACUUM/CARRIER
GAS
A vacuum is created in the treatment chamber using a 75 horsepower
vacuum fan. The fan unit is rated to transfer 6,500 cfm of
air at 95 inches of water column vacuum.
One
benefit of operating the MCS under vacuum conditions is that
the amount of energy required to desorb the target compounds
is significantly reduced when compared to removing these contaminants
at atmospheric pressure. A second benefit of operating the
MCS under vacuum conditions is that the low operating temperatures
of the system minimizes the potential production of thermal
degradation products.
Essentially,
the contaminants undergo a phase change from the liquid phase
to a vapor phase and them return to the liquid phase; there
are no changes in the chemical structure of the contaminants.
The
MCS system uses the air flow created by the vacuum blower
as a carrier gas stream to transport the desorbed water and
chemicals from the treatment chamber to an emission control
system consisting of a series of nondestructive devices.
The
primary function of the carrier gas stream is to convey the
desorbed contaminants from the treatment chamber to the emission
control system and to convect heat through the mass in the
treatment chamber. A second function of the carrier gas stream
is to enhance the desorption of the water and contaminants
from the matrix. Similar to reducing the pressure in the treatment
chamber, evacuated air cascading through the matrix reduces
the boiling point of both the contaminants and the water;
an effect referred to as air stripping. The net result is
shorter treatment times and lower energy costs.
A
third function of the carrier gas stream is to enhance the
transport of the infrared energy through the matrix. The upward
flow of air helps to convey the thermal energy from the bottom
several inches of material to overlying layers. Since this
convective heat transfer will adhere to classical physical
laws, the parameters regulating the rate of this transfer
to the overlying layers is the temperature differential between
the various mediums and the velocity of the carrier gas.
EMISSION
CONTROLS
A variety of air emission control options are available, depending
on the type of chemical and condition of the carrier stream.
Condition refers to the temperature, pressure, volume, chemicals
and moisture content. Air handling options include:
Dry
Particulate Filter (DPF) Used to minimize dust
accumulation in downstream air emission control components
(i.e. condenser, coalescing media, carbon units) and eliminate
particulate emissions to the atmosphere. Certain types of
contaminants, such as heavy fuel oils, asphalt-like substances,
wood, and other combustible organic debris can generate smoke.
The release of smoke is controlled by microfiltration.
Condenser
and Chiller Temperatures of the air stream exiting
the treatment chamber can range from 175° to 800°
F. Carbon treatment units are ineffective at these temperatures;
therefore a condenser or cool down chamber is required. The
condenser, which is connected to an appropriately sized chiller,
reduces the air temperature to approximately 40° F. Selection
of a chiller is based upon the inlet temperature, outlet temperature
requirements, and airflow. The condenser is connected via
a transfer pump to an appropriately sized storage vessel for
the collected condensate. The condensate is treated and the
products can be recycled or concentrated for proper disposal.
Activated Carbon The MCS system is equipped with
the necessary size and number of carbon polishing units
to achieve the desired result. Carbon units provide the
final polishing of the air stream prior to discharge to
the atmosphere.
Coalescing Filter This filter is incorporated
within the condenser unit to consolidate small liquid particulates
into larger droplets which condense on the opposite side
of the centured metal media of the coalescing filter and
are collected as purified product.
Scrubber Systems For mercury and cyanide containing
matrices, a packed tower and countercurrent scrubber system
is used in conjunction with an acidified or caustic fluid
to absorb or dissolve residual contaminants as either a
primary or polishing step (depends on the specific application).
Air Sampling Air samples are collected as required
to monitor the proper functioning of the emission control
system. Individual states have specific emissions monitoring
requirements, which are normally contained in discharge
permits. At a minimum, one stack test is usually performed
at the start of a project. This involves a complete treatment
cycle. Air samples are collected after the final carbon
unit prior to discharge to atmosphere.
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